The fundamental components of glass melting furnaces and kilns are
refractory materials, which have a significant impact on glass quality,
energy consumption, and manufacturing costs. The advancement of
refractory production technology and the improvement of refractory
product quality will have an impact on the future of glass melting
technology.
- Refractory fire clay brick: Fire clay
bricks are composed mainly of Al2O3. The Al2O3 content is between 30 and
45%; density ranges from 1.7 and 2.4G/cm3; apparent porosity ranges
from 11 to 22%; the most working temperature is 1350 to 1520°C. In glass
manufacturing, fire clay bricks are generally suitable for regions such
as the base of the furnace, the working poll’s sidewall and its lateral
wall, the crown, and the regenerator’s lower layers, and the fire
chimney. The volume of fire clay bricks will likewise increase if the
temperature rises. The volume will decrease again when the temperature
exceeds 1450°C.
- Silica Bricks: Silicon dioxide is the major
component of silica brick (SiO2). The glass melting furnace requires a
silica brick with a SiO2 content of at least 94 percent, a maximum
working temperature of roughly 1600-1650°C, and a density of around
1.81.95g/cm3. The apparent porosity of the material must be less than
22%. The lower the apparent porosity, the lower the grade of silica
brick. In the glass melting furnace, it’s mostly used for the crown and
breast walls.
- Refractory High Alumina Bricks: Al2O3 is
likewise the main component of refractory high alumina bricks, however,
the content of Al2O3 should be higher than 46 percent, often between 46
and 80 percent. High alumina bricks have a density of 2.553.0g/cm3, an
apparent porosity of 18%–24%, and a maximum operating temperature of
1500°–1650°C. Corrosion resistance is better when the apparent porosity
of the high alumina brick is low. For the sidewall of the cooling cool,
the regenerator crown, and the regenerator walls, high-alumina bricks
can be utilized.
- Fused Cast AZS Bricks: The proportion of
ZrO2 in fused cast AZS (Alumina Zirconia Silica) bricks (electro-fused
zirconia corundum bricks) is commonly split into three types: 33
percent, 36 percent, and 41 percent. The zirconia corundum bricks used
in the glass furnace application have a 50 percent Al2O3 content and a
20 percent ZrO2 content. The bulk density is 3.44.0g/cm3, the apparent
porosity is 1%–10%, and the maximum use temperature is approximately
1700°C. Fused cast AZS bricks with 33 percent and 36 percent ZrO2
content are typically used for melter side walls, breast walls, pavement
blocks, ports, and tongues, among other applications.
- Refractory Insulation Bricks: In order to
save energy and reduce consumption, a significant volume of insulation
materials is necessary for comprehensive heat preservation in the glass
melting furnace when the heat dissipation region and the thermal
efficiency are low. To reduce heat dissipation, the regenerator, melter,
working end, and other components must be insulated on the sidewall,
bottom, crown, and walls. Insulation brick has a high apparent porosity,
a lightweight, and a bulk density of less than 1.3g/cm3. The thermal
insulation brick with a wide apparent porosity has a thermal insulation
effect because the heat transfer performance of air is very poor.
Because its heat conductivity is 2 to 3 times that of common refractory
materials, the higher the apparent porosity, the better the insulation
effect. Insulation bricks come in a variety of shapes and sizes,
including fire clay insulation bricks, silicon insulation bricks, and
high alumina thermal insulation bricks, among others.
- Refractory Mullite Bricks: Mullite
refractory bricks are mostly composed of Al2O3, with an Al2O3 content of
roughly 75%. Because it is primarily mullite crystal, so it refers to
as mullite brick. The density ranges from 2.2 to 3.2g/cm3, the apparent
porosity ranges from 1% to 12%, and the maximum operating temperature
ranges from 1500 to 1700 degrees Celsius. The sidewalls of regenerators
are mostly made of sintered mullite. Fused mullite is commonly used on
the sidewalls of cooling towers, observation holes, and wall stacks,
among other things.
- Refractory Alkaline Materials: Magnesia
bricks, aluminium magnesia bricks, magnesia chrome bricks, and
forsterite bricks are commonly used alkaline refractory materials. Its
refractoriness ranges from 1900 to 2000 degrees Celsius, and it has
exceptional corrosion resistance to alkaline compounds. It’s common in
the upper wall of the glass melting furnace’s regenerator, the
regenerator wall, the regenerator checker, and the port’s partial
structure.
- Fused Corundum Bricks: It refers majorly to
refractory fused-cast corundum bricks, having mostly 92% ~ 94% Al2O3
corundum crystal phase, its volume density is 2.9 ~ 3.0g/cm3, and their
apparent porosity lies between 1% ~ 10% & the highest operating
temperature is about 1700°C. Fused alumina has a high resistance to
glass dialysis and pollutes molten glass very little. It’s commonly used
for sidewalls of working polls, bottom pavings, forehearths, throats,
and feeder walls in glass melting furnaces, among other things, that are
connected with liquid glass and do not require liquid contamination.
- Quartz bricks: Quartz bricks consist
predominantly of SiO2, with a maximum concentration of more than 99%, a
1.9 ~ 2g/cm3 density, a 1650°C refractoriness, work temperatures of
around 1600°C, and corrosion resistance to acidic matter. It is used for
building the acid boron glass pool wall. Thermocouple flame spacing
bricks hole, etc.
Conclusion
The glass melting furnaces are industrial installations within
which complex and interconnected physical and chemical phenomena occur.
To improve the functioning and quality of the produced glass, the
relationship between heat transfers and flows into the melted glass, the
interaction of heat transfers and the thermal control of the furnace,
the relationship of heat transfers to the quality of the glass, and heat
transfer between molten glass, the furnace walls, etc. must be
studied.Refractory manufacturers in India are constantly working in
Research & Development to provide the best quality refractory
products for Glass manufacturing Industry.